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    2. Grade R50700

    ASTM F468/F468M Grade R50700 4 Titanium Gr 4 Fasteners

    High quality ASTM F468 Titanium Gr 4 fasteners manufactured for industrial and corrosion resistant applications.

    ASTM F468/F468M Grade R50700 Titanium Gr 4 fasteners are manufactured in accordance with ASTM specifications for nonferrous bolts, hex cap screws, socket head cap screws, and studs.

    Chemical Requirements

    UNS Designation Number Alloy General Name Al C Fe Ti H N O Pd V Cr Mo Zr Sn Si Ru Residuals B
    Each, max Total, max
    Grade R50700 4 Titanium Gr 4 . . . 0.10 0.50 balance 0.0125 0.07 0.40 . . . . . . . . . . . . . . . . . . . . . . . . 0.1 0.4
    • (A) All reported values are maximums, unless a range is specified.
    • (B) A residual is an element present in a metal or an alloy in small quantities inherent to the manufacturing process but not added intentionally. Residual elements need not be reported unless a report is specifically required by the purchaser.
    • (C) Identical chemical requirements apply to both Class A and B as defined in Table 2 and 6.5.
    • (D) Ruthenium and palladium, or both, may be added to Grade 19 for enhanced corrosion resistance as negotiated between purchaser and vendor. Chemical analysis is not required unless specifically required by the purchaser.

    Mechanical Requirements

    Alloy Mechanical Property Marking Nominal Thread Diameter, in. Hardness A Full-Size Tests B Machined Specimen Tests
    Tensile Strength, ksi Yield Strength, min, ksi C Tensile Strength, min, ksi Yield Strength min, ksi C Elongation in 4D, min, % D
    Alloy Ti 4 F468CT All 200-220 HV 80-115 75 80 70 15
    • (A) Where both tension and hardness tests are performed, the tension tests shall take precedence for acceptance purposes. For aluminum and titanium alloys, hardness tests are for information only. See 6.5.
    • (B) The yield and tensile strength values for full-size products shall be computed by dividing the yield and maximum tensile load by the stress area for the product diameter and thread pitch as given in table on tensile stress areas.
    • (C) Yield strength is the stress at which an offset of 0.2 % gage length occurs.
    • (D) Elongation is determined using a gage length of 4 diameters of test specimen in accordance with Test Methods E8/E8M.
    • (E) "HF" denotes a hot-formed product.
    • (F) Aluminum alloy temper designations are in accordance with ANSI H35.1.
    • (G) Full-size test mechanical properties apply to fasteners with a maximum diameter of 76 mm. Mechanical properties of larger sections shall be negotiated between the material manufacturer and the fastener producer.
    • (H) Ti 5 Class A requires wedge tensile testing in accordance with Ti 5 Class B requires wedge tensile testing in accordance.

    ASTM F468/F468M Grade R50700 4 Titanium Gr 4 Tensile Stress Areas and Threads(Inch)

    Nominal Size, in. Coarse Threads-UNC Fine Threads-UNF 8 Thread Series-8UN
    Threads/ in. Stress Area A , in. 2 Threads/ in. Stress Area A , in. 2 Threads/ in. Stress Area A , in. 2
    1 / 4 20 0.0318 28 0.0364 . . . . . .
    5 / 16 18 0.0524 24 0.0580 . . . . . .
    3 / 18 16 0.0775 24 0.0878 . . . . . .
    7 / 16 14 0.1063 20 0.1187 . . . . . .
    1 / 2 13 0.1419 20 0.1599 . . . . . .
    9 / 16 12 0.1820 18 0.2030 . . . . . .
    5 / 8 11 0.2260 18 0.2560 . . . . . .
    3 / 4 10 0.3340 16 0.3730 . . . . . .
    7 / 8 9 0.4620 14 0.5090 . . . . . .
    1 8 0.6060 12 0.6630 . . . . . .
    1 1 / 8 7 0.7630 12 0.8560 8 0.790
    1 1 / 4 7 0.9690 12 1.0730 8 1.000
    1 3 / 8 6 1.1550 12 1.3150 8 1.233
    1 1 / 2 6 1.4050 12 1.5810 8 1.492
    • (A) Tensile stress areas are computed using the following formula:
    • A s = 0.7854 [ D - 0.9743/n ]
    • where:
    • As = tensile stress area, in.2,
    • D = nominal size (basic major diameter), in., and
    • n = number of threads per inch.

    ASTM F468/F468M Grade R50700 4 Titanium Gr 4 Tensile Stress Areas (Metric)

    Nominal Product Diameter and Thread Pitch Stress Area, A mm 2 Nominal Product Diameter and Thread Pitch Stress Area, A mm 2
    M6 × 1 20.1 M16 × 2 157
    M8 × 1.25 36.6 M20 × 2.5 245
    M10 × 1.5 58.0 M24 × 3 353
    M12 × 1.75 84.3 M30 × 3.5 561
    M14 × 2 115 M36 × 4 817
    • (A) Tensile stress areas are computed using the following formula:
    • A s = 0.7854 (D − 0.9382 P) 2
    • where:
    • As = stress area, mm2,
    • D  = nominal thread diameter, mm, and
    • P  = thread pitch, mm.

    Frequently Asked Questions

    What is Titanium Grade 4 (R50700)?

    Grade 4 is the strongest commercially-pure titanium per ASTM F468 (oxygen 0.40% max). Tensile 80 ksi min, yield 70 ksi min, elongation 15% min. Used where high CP-titanium strength is needed - aerospace airframe brackets, high-pressure heat exchanger bolting, and dental + medical applications.

    How does Grade 4 compare to Grade 5 (Ti-6Al-4V)?

    Grade 4 is unalloyed (Ti only) so it retains the full corrosion resistance of CP titanium with about 70% the strength of Grade 5. Grade 5 adds aluminum + vanadium for an additional 30% tensile / 60% yield strength at the cost of slightly more crevice + chloride sensitivity. Choose Gr 4 for corrosion-critical applications, Gr 5 for strength-critical.

    Sour-service acceptance?

    Yes - all titanium grades are NACE MR0175-listed with normal acceptance criteria.

    Where is Grade 4 used in F468 bolting?

    Aerospace structural fasteners, high-pressure plate heat-exchanger bolting (Grade 4 plates need Grade 4 bolts to avoid galvanic mismatch), and specialty chemical-process applications requiring CP-Ti corrosion with higher strength.

    References & Standards

    • ASTM F468 / F468M - Standard Specification for Nonferrous Bolts, Hex Cap Screws, and Studs for General Use
    • ASTM F467 / F467M - Companion specification for Nonferrous Nuts (mate with F468 for matched-alloy assemblies)
    • ASTM F436 / F436M - Hardened steel washers (ferrous washer companion when nonferrous washers are not specified)
    • NACE MR0175 / ISO 15156 - Sour-service hardness limits for petroleum and natural gas industries
    • ASME B18.2.1 / B18.2.3 series / B18.3 / B18.6.7M / B18.31 / B16.5 - Dimensional standards referenced by F468
    • DIN 912 / 933 / 931 - Metric hex socket head and hex head cap screw dimensional standards
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